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Monday, February 9, 2009

Colour

Main article: Diamond color
Brown colored diamonds at the National Museum of Natural History

Gem quality diamond may be colorless or occur in any hue including the non-spectral hues of gray, brown and black. Diamond is the only gemstone composed of a single element, carbon. The diamond crystal lattice is exceptionally strong and only atoms of nitrogen, boron, hydrogen, phosphorus and maybe beryllium can be introduced into diamond during the growth at significant concentrations. Transition metals Ni and Co, which are commonly used for growth of synthetic diamond by the high-pressure high-temperature techniques, have been detected in diamond as individual atoms, however the maximum concentration is 0.01% for Ni[14] and even much less for Co. Note however, that virtually any element can be introduced in diamond by ion implantation.

Nitrogen is the smallest and by far the most common impurity found in gem diamonds. Nitrogen is responsible for the yellow and brown in diamonds. Boron is responsible for the gray blue colors. Color in diamond has two additional sources: irradiation (usually by alpha particles), that causes the color in green diamonds; and physical deformation of the diamond crystal known as plastic deformation. Plastic deformation is the cause of color in some brown[15] and perhaps pink and red diamonds.[16] In order of rarity, colorless diamond, by far the most common, is followed by blue, green, black, translucent white, pink, violet, orange, purple and red, though yellow and brown are by far the most common colors.[10] "Black," or Carbonado, diamonds are not truly black, but rather contain numerous dark inclusions that give the gems their dark appearance. Colored diamonds contain impurities or structural defects that cause the coloration, while pure or nearly pure diamonds are transparent and colorless. Most diamond impurities replace a carbon atom in the crystal lattice, known as a carbon flaw. The most common impurity, nitrogen, causes a slight to intense yellow coloration depending upon the type and concentration of nitrogen present.[10] The Gemological Institute of America (GIA) classifies low saturation yellow and brown diamonds as diamonds in the normal color range, and applies a grading scale from 'D' (colorless) to 'Z' (light yellow). Diamonds of a different color, such as blue, are called fancy colored diamonds, and fall under a different grading scale.

In 2008, the Wittelsbach Diamond, a 35.56 carats (7.11 g) blue diamond once belonging to the King of Spain, fetched over $24M US at a Christie's auction. The blue hue was a result of trace amounts of boron in the stone's crystal structure.[17]

Identification

Diamonds can be identified by their high thermal conductivity. Their high refractive index is also indicative, but other materials have similar refractivity. Diamonds do cut glass, but other materials above glass on Mohs scale such as quartz do also. Diamonds easily scratch other diamonds, but this damages both diamonds.

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